12113-37-0

Basic information

• Product Name: titanium(4+) chloride 4,5,6,7-tetrahydroinden-3a-ide (1:2:2)
• CAS NO: 12113-37-0
• Molecular Formula: C₁₈H₂₂Cl₂Ti
• Molecular Weight: 357.1403
• Mol File: 12113-37-0.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 189.7°C at 760 mmHg
• Flash Point: 45.6°C
• Vapor Pressure: 0.776mmHg at 25°C
• CAS DataBase Reference: titanium(4+) chloride 4,5,6,7-tetrahydroinden-3a-ide (1:2:2)(CAS DataBase Reference)
• NIST Chemistry Reference: titanium(4+) chloride 4,5,6,7-tetrahydroinden-3a-ide (1:2:2)(12113-37-0)
• EPA Substance Registry System: titanium(4+) chloride 4,5,6,7-tetrahydroinden-3a-ide (1:2:2)(12113-37-0)

Safety Data

• Hazardous Substances Data: 12113-37-0(Hazardous Substances Data)

Upstream product

• 7550-45-0 titanium tetrachloride 
• 24279-06-9 bicyclo<4.3.0>nona-1(6),7-diene 

Downstream Products

• 205586-35-2 (tetrahydroindenyl)2Ti(η(2)-phenyl(trimethylsilyl)acetylene) 

Relevant articles and documents

Synthesis of ring-substituted bis-η5-cyclopentadienyl derivatives of the Group IV elements containing the bicyclic ligands η5-C5H3(1,2-CH2-)n, n=4, 5, or 6

The synthesis of unsubstituted and substituted bicyclic η5-cyclopentadienyl ligands and their Group IV metal complexes [M{η5-C5H3(1,2-CH2-) n}2Cl2], where n=4, 5, 6 and M=Ti, Zr, Hf, is reported. An example of an ansa-bridged zirconium analogue is also described.