121153-31-9

Basic information

• Product Name: Benzene, [[[[(1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl]oxy]methyl]thio]-
• CAS NO: 121153-31-9
• Molecular Formula: C17H26OS
• Molecular Weight: 278.459
• Mol File: 121153-31-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, [[[[(1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl]oxy]methyl]thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[[[(1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl]oxy]methyl]thio]-(121153-31-9)
• EPA Substance Registry System: Benzene, [[[[(1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl]oxy]methyl]thio]-(121153-31-9)

Safety Data

• Hazardous Substances Data: 121153-31-9(Hazardous Substances Data)

Upstream product

• 17314-33-9 tributyltin phenyl sulfide 
• 123482-46-2 methoxyethoxymethyl ether of menthol 
• 121153-32-0 (-)-menthol-MOM 
• 16849-85-7 (1R,1'R,2S,2'S,5R,5'R)-1,1'-methylenedioxybis(2-isopropyl-5-methylcyclohexane) 
• 2216-51-5 (-)-menthol 
• 26127-08-2 (1R,2S,5R)-1-(chloromethoxy)-2-isopropyl-5-methylcyclohexane 
• 108-98-5 thiophenol 

Relevant articles and documents

Synthesis of dithioacetals and oxathioacetals with chiral auxiliaries

One-pot synthesis of dithioacetals as well as an efficient method for oxathioacetal is reported. Additionally, some chiral auxiliaries were used to synthesize enantiomerically pure dithioacetals and oxathioacetals.

ACTIVATION AND SYNTHETIC APPLICATIONS OF THIOSTANNANES. THIOALKOXYLATION OF ACETALS

The Sn-S bonds in thiostannanes, BunSn(SPh)4-n, are activated towards acetals in the presence of BF3*OEt2.Acetals of various aldehydes and ketones are converted into the corresponding monothioacetals under mild conditions.Employment of α-enal acetals induces Michael addition to give synthetically useful γ-alkoxyally sulfides.