121289-23-4

Basic information

• Product Name: Acetaldehyde, [(4-methoxyphenyl)methoxy]-
• CAS NO: 121289-23-4
• Molecular Formula: C10H12O3
• Molecular Weight: 180.203
• Mol File: 121289-23-4.mol
• Article Data: 39

Chemical Properties

• CAS DataBase Reference: Acetaldehyde, [(4-methoxyphenyl)methoxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetaldehyde, [(4-methoxyphenyl)methoxy]-(121289-23-4)
• EPA Substance Registry System: Acetaldehyde, [(4-methoxyphenyl)methoxy]-(121289-23-4)

Safety Data

• Hazardous Substances Data: 121289-23-4(Hazardous Substances Data)

Upstream product

• 179548-99-3 (Z)-1,4-bis((4-methoxybenzyl)oxy)but-2-ene 
• 109786-74-5 (±)-3-(4-methoxybenzyloxy)propane-1,2-diol 
• 824-94-2 p-methoxybenzyl chloride 
• 2746-25-0 p-Methoxybenzyl bromide 
• 156147-59-0 4-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolane 
• 51759-07-0 (4-methoxybenzyloxy)acetic acid methyl ester 
• 105-13-5 4-Methoxybenzyl alcohol 
• 143833-81-2 (Z)-4-(4-methoxybenzyloxy)but-2-en-1-ol 
• 13807-89-1 2-(4-methoxybenzyloxy)ethanol 
• 114809-55-1 1,4-bis<(4-methoxybenzyl)oxy>but-2-ene 
• 14289-62-4 1-(allyloxymethyl)-4-methoxybenzene 
• 57938-80-4 ethyl 2-((4-methoxybenzyl)oxy)acetate 

Downstream Products

• 130252-82-3 1-p-methoxybenzyloxy-3-methylbut-3-en-2-ol 
• 121289-24-5 (S)-1-[(1S,3S,5R)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methylene-cyclohexyl]-2-(4-methoxy-benzyloxy)-ethanol 
• 147438-56-0 (E)-(S)-1-Hydroxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-en-3-one 
• 1058161-91-3 (R)-4-benzyl-3-((R)-2-((R)-1-hydroxy-2-(4-methoxybenzyloxy)ethyl)hexanoyl)oxazolidin-2-one 
• 1109277-74-8 [2-(4-methoxybenzyloxy)ethylidene]methamine oxide 
• 1044871-72-8 (2S,4Z)-1-(4'-methoxybenzyloxy)hept-4-en-2-ol 
• 155626-52-1 (2R,4Z)-1-(4'-methoxybenzyloxy)hept-4-en-2-ol 
• 1044871-63-7 (2S,4Z)-7-(tert-butyldimethylsilyloxy)-1-(4''-methoxybenzyloxy)hept-4-en-2-ol 
• 1044871-65-9 (2R,4Z)-7-(tert-butyldimethylsilyloxy)-1-(4''-methoxybenzyloxy)hept-4-en-2-ol 
• 1203447-52-2 1-((3,3-dibromoallyloxy)methyl)-4-methoxybenzene 
• 1182221-94-8 (S,E)-methyl 2-ethyl-6-(4-methoxybenzyloxy)-2-methyl-3-oxohex-4-enoate 
• 1182222-21-4 (R,E)-methyl 2-ethyl-6-(4-methoxybenzyloxy)-2-methyl-3-oxohex-4-enoate 
• 1299293-73-4 ethyl (2E,4S,5R)-5-{[tert-butyl(dimethyl)silyl]oxy}-6-[(4-methoxybenzyl)oxy]-4-methylhex-2-enoate 
• 1299293-74-5 ethyl (4S,5R)-5-{[tert-butyl(dimethyl)silyl]oxy}-6-[(4-methoxybenzyl)oxy]-4-methylhexanoate 

Relevant articles and documents

Compound as well as preparation method and medical application thereof

The invention provides a compound as well as a preparation method and medical application thereof, the compound has a structure as shown in a general formula (I), and can also be a tautomer, a mesomer, a raceme, an enantiomer, a diastereoisomer, or a mixture form thereof, or a pharmaceutically acceptable salt thereof. According to the compound with the structure as shown in the general formula (I)provided by the invention, a specific main chain structure and a corresponding substituent group are selected, so that the obtained compound can be used as an arginase inhibitor, is relatively high in activity, and has a potential treatment prospect in various diseases.

Substrate specificity of tuliposide-converting enzyme, a unique non-ester-hydrolyzing carboxylesterase in tulip: Effects of the alcohol moiety of substrate on the enzyme activity

6-Tuliposides A (PosA) and B (PosB) are glucose esters accumulated in tulip (Tulipa gesneriana) as major defensive secondary metabolites. Pos-converting enzymes (TgTCEs), which we discovered previously from tulip, catalyze the conversion reactions of PosA

Enzyme-mediated enantioselective hydrolysis of 1,2-diol monotosylate derivatives bearing an unsaturated substituent

We have succeeded in the easy preparation of optically active 1,2-diol monotosylates bearing an unsaturated substituent via enzymatic hydrolysis. Lipase PS quickly catalyzes the hydrolyses of 2-acetoxybut-3-enyl tosylate, which has a double bond, and 2-acetoxybut-3-ynyl tosylate, which has a triple bond, with excellent enantioselectivity to afford the corresponding optically active compounds. The reaction is also applicable to acetates with a longer chain, which has a double bond at the terminus. To demonstrate the applicability of this method, enantiomerically pure (R)-massoialactone, a natural coconut flavor, has been synthesized from racemic 2-acetoxypent-4-enyl tosylate in several steps. Furthermore, the enzyme can recognize the stereochemistry of olefins, and the (Z)-alkenyl structure is more suitable for the enantioselective hydrolysis than the (E)-isomer.