1214273-28-5Relevant articles and documents
Nickel-catalyzed bolylation of aryl halides with 4,4,6-trimethyl-1,3,2- dioxaborinane
Murata, Miki,Sogabe, Yosuke,Namikoshi, Takeshi,Watanabe, Shinji
, p. 133 - 138 (2013/08/23)
The nickel-catalyzed borylation of aryl iodides and bromides with 4,4,6-trimethyl-1,3,2-dioxaborinane was achieved. The mild reaction conditions employed allowed for the inclusion of common functional groups in aryl halides to be tolerated. A DFT study on the catalytic cycle shows that C-B bond formation occurs through s-bond metathesis between dialkoxyborane and arylnickel(II) halide intermediates.