121613-97-6

Basic information

• Product Name: 2-(dimethylamino)-N-methyl-diphenylamine
• Synonyms: 2-(dimethylamino)-N-methyl-diphenylamine
• CAS NO: 121613-97-6
• Molecular Weight: 226.321
• Mol File: 121613-97-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(dimethylamino)-N-methyl-diphenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(dimethylamino)-N-methyl-diphenylamine(121613-97-6)
• EPA Substance Registry System: 2-(dimethylamino)-N-methyl-diphenylamine(121613-97-6)

Safety Data

• Hazardous Substances Data: 121613-97-6(Hazardous Substances Data)

Upstream product

• 124-38-9 carbon dioxide 
• 534-85-0 N-phenyl-1,2-benzenediamine 
• 98-60-2 4-chlorobenzenesulfonyl chloride 
• 864512-14-1 2-iodophenyl 4-chlorobenzenesulfonate 
• 58105-38-7 O-benzoyl N,N-dimethylhydroxylamine 
• 100-61-8 N-methylaniline 
• 119-75-5 2-nitro-N-phenylaniline 
• 121-45-9 phosphorous acid trimethyl ester 

Relevant articles and documents

Double heteroatom functionalization of arenes using benzyne three-component coupling

Arynes participate in three-component coupling reactions with N, S, P, and Se functionalities to yield 1,2-heteroatom-difunctionalized arenes. Using 2-iodophenyl arylsulfonates as benzyne precursors, we could effectively add magnesiated S-, Se-, and N-nucleophilic components to the strained triple bond. In the same pot, addition of electrophilic N, S, or P reagents and a copper(I) catalyst trapped the intermediate aryl Grignard to produce a variety of 1,2- difunctionalized arenes.

1,3-DIHYDRO-1,3,2-DIAZAPHOSPHOLE 2-OXIDES. A CONVENIENT ONE-POT-SYNTHESIS FROM 2-NITRODIPHENYLAMINES AND TRIALKYL PHOSPHITES

Reductive cyclization of 2-nitrodiphenylamines with trialkyl phosphites provides an efficient one-pot synthesis of 1,3-dihydro-1,3,2-diazaphosphole 2-oxides.Further exhaustive alkylation at elevated temperature is accompanied by rupture of both P-N bonds,