121732-94-3

Basic information

• Product Name: 3,5-Cyclohexadiene-1,2-dione, 3,4,5-trimethoxy-
• CAS NO: 121732-94-3
• Molecular Formula: C9H10O5
• Molecular Weight: 198.175
• Mol File: 121732-94-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3,5-Cyclohexadiene-1,2-dione, 3,4,5-trimethoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-Cyclohexadiene-1,2-dione, 3,4,5-trimethoxy-(121732-94-3)
• EPA Substance Registry System: 3,5-Cyclohexadiene-1,2-dione, 3,4,5-trimethoxy-(121732-94-3)

Safety Data

• Hazardous Substances Data: 121732-94-3(Hazardous Substances Data)

Upstream product

• 642-71-7 3,4,5-trimethoxyphenol 

Relevant articles and documents

A New Synthesis of ortho-Quinones by Transition-Metal-Mediated Oxygenation of Phenols with tert-Butylhydroperoxide and the Mimoun Oxodiperoxo Molybdenum Complex * Py * HMPT

A specific oxygenation of phenols to ortho-quinones can be effected by a combination of the transition metal complexes Ti(OiPr)4, VO(acac)2, Zr(acac)4, Zr(OnPr)4 and tert-butylhydroperoxide (TBHP) or * Py * HMPT.Naphthols, anthracenols, phenanthrols and donor substituted mononuclear phenols are readily converted into the corresponding 1,2-quinones.Unhindered ortho-naphthoquinones can yield binaphthyls with unreacted starting material by Michael addition. - Key Words: ortho-Quinones / tert-Butyl hydroperoxide / Phenols, oxygenation