121740-77-0

Basic information

• Product Name: 2,2-dicinnamyl-1,3-cyclohexanedione
• Synonyms: 2,2-dicinnamyl-1,3-cyclohexanedione
• CAS NO: 121740-77-0
• Molecular Weight: 344.453
• Mol File: 121740-77-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,2-dicinnamyl-1,3-cyclohexanedione(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-dicinnamyl-1,3-cyclohexanedione(121740-77-0)
• EPA Substance Registry System: 2,2-dicinnamyl-1,3-cyclohexanedione(121740-77-0)

Safety Data

• Hazardous Substances Data: 121740-77-0(Hazardous Substances Data)

Upstream product

• 504-02-9 1,3-cylohexanedione 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 62269-48-1 3-[(trimethylsilyl)oxy]cyclohex-2-en-1-one 
• 106625-69-8 ethyl (E)-3-phenyl-2-propenyl carbonate 
• 30182-67-3 1,3-Cyclohexanedione 
• 21040-45-9 Cinnamyl acetate 

Relevant articles and documents

Dual platinum and pyrrolidine catalysis in the direct alkylation of allylic alcohols: Selective synthesis of monoallylation products

A dual platinum- and pyrrolidine-catalyzed direct allylic alkylation of allylic alcohols with various active methylene compounds to produce products with high monoallylation selectivity was developed. The use of pyrrolidine and acetic acid was essential, not only for preventing undesirable side reactions, but also for obtaining high monoallylation selectivity. Two cats are better than one: The combined use of platinum and pyrrolidine catalysts enabled the direct alkylation of allylic alcohols with reactive methylene compounds. Pyrrolidine was essential for obtaining high selectivity of the monoallylation products, which were produced without the use of excess nucleophiles. cod=1,5- cyclooctadiene, EWG=electron-withdrawing group.

PALLADIUM CATALYZED C-ALLYLATION OF HIGHLY ACIDIC CARBO AND HETEROCYCLIC β-DICARBONYL COMPOUNDS

Highly acidic carbo and heterocyclic β-dicarbonyl compounds such as barbituric acid, 3,5-dimethyl-2H-1,2,6-thiadiazine 1,1-dioxide, cyclohexane-1,3-dione, tetronic acids, Meldrum acid and 1,2-diphenylpyrazolidine-3,5-dione are efficiently C-allylated with primary and secondary allylating agents under palladium catalysis.