1217489-63-8

Basic information

• Product Name: triisopropyl-(4-vinyl-benzyloxy)-silane
• Synonyms: triisopropyl-(4-vinyl-benzyloxy)-silane
• CAS NO: 1217489-63-8
• Molecular Weight: 290.521
• Mol File: 1217489-63-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: triisopropyl-(4-vinyl-benzyloxy)-silane(CAS DataBase Reference)
• NIST Chemistry Reference: triisopropyl-(4-vinyl-benzyloxy)-silane(1217489-63-8)
• EPA Substance Registry System: triisopropyl-(4-vinyl-benzyloxy)-silane(1217489-63-8)

Safety Data

• Hazardous Substances Data: 1217489-63-8(Hazardous Substances Data)

Upstream product

• 13154-24-0 triisopropylsilyl chloride 
• 1074-61-9 (4-vinyl-phenyl)-methanol 

Downstream Products

• 1391734-28-3 N-(4-nitrobenzenesulfonyl)-2(R)-(2,4-dichlorophenyl)-5(S)-(4-triisopropylsilanyloxymethylphenyl)-1,3-oxazolane 

Relevant articles and documents

Iron-catalyzed aminohydroxylation of olefins

We have discovered that N -sulfonyl oxaziridines react with a broad range of olefins in the presence of iron salts to afford 1,3-oxazolidines. This process provides access to 1,2-aminoalcohols with the opposite sense of regioselectivity produced from the copper-catalyzed oxyamination previously reported by our laboratories. Thus, either regioisomeric form of 1,2-aminoalcohols can easily be obtained from the reaction of oxaziridines with olefins, and the sense of regioselectivity can be controlled by the appropriate choice of inexpensive, nontoxic, first-row transition-metal catalyst.