121794-40-9

Basic information

• Product Name: Benzoyl chloride, 2-bromo-3-methyl-
• CAS NO: 121794-40-9
• Molecular Formula: C8H6BrClO
• Molecular Weight: 233.492
• Mol File: 121794-40-9.mol
• Article Data: 25

Chemical Properties

• CAS DataBase Reference: Benzoyl chloride, 2-bromo-3-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoyl chloride, 2-bromo-3-methyl-(121794-40-9)
• EPA Substance Registry System: Benzoyl chloride, 2-bromo-3-methyl-(121794-40-9)

Safety Data

• Hazardous Substances Data: 121794-40-9(Hazardous Substances Data)

Upstream product

• 84392-25-6 4'-(propan-2-yl)[1,1'-biphenyl]-2-carboxylic acid 
• 53663-39-1 3-methyl-2-bromobenzoic acid 

Downstream Products

• 121794-45-4 2-Bromo-3-methyl-benzoic acid 4-hydroxy-butyl ester 
• 924660-38-8 N-benzyl-2-bromo-3-methylbenzamide 
• 121794-43-2 2-Bromo-3-methyl-benzoic acid 2-hydroxy-ethyl ester 

Relevant articles and documents

Synthesis of Axially Chiral 2,2′-Bisphosphobiarenes via a Nickel-Catalyzed Asymmetric Ullmann Coupling: General Access to Privileged Chiral Ligands without Optical Resolution

We report an asymmetric homocoupling of ortho-(iodo)arylphosphine oxides and ortho-(iodo)arylphosphonates resulting in highly enantioenriched axially chiral bisphosphine oxides and bisphosphonates. These products are readily converted to enantioenriched b

Kinetic Resolution of Tertiary Benzyl Alcohols via Palladium/Chiral Norbornene Cooperative Catalysis

Herein we report a highly enantioselective kinetic resolution of tertiary benzyl alcohols via palladium/chiral norbornene cooperative catalysis. With simple aryl iodides as the resolution reagent, a wide range of readily available racemic tertiary benzyl alcohols are applicable to this method. Both chiral tertiary benzyl alcohols and benzo[c]chromene products are obtained in good to excellent enantioselectivities (selectivity factor up to 544). The appealing synthetic utility of the obtained enantioenriched tertiary alcohols is demonstrated by the facile preparation of several valuable chiral heterocycles. Preliminary mechanism studies include DFT calculations to explain the origin of enantiodiscrimination and control experiments to uncover the formation of a transient axial chirality during the kinetic resolution step.

Benzoheterocycle substituted phenanthridine quaternary ammonium salt derivative as well as preparation method and application thereof

The invention discloses a benzoheterocycle substituted phenanthridine quaternary ammonium salt derivative and a preparation method and application thereof, the benzoheterocycle substituted phenanthridine quaternary ammonium salt derivative has a structure