1218812-66-8Relevant articles and documents
Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes
Zeng, Xiaoming,Kinjo, Rei,Donnadieu, Bruno,Bertrand, Guy
supporting information; experimental part, p. 942 - 945 (2010/06/11)
(Chemical equation presented) The gold rush: A cationic gold (I) complex, supported by a CAAC ligand, promotes the intramolecular addition of N-H or N-Me bonds (from ammonium salts or tertiary amines, respectively) to carbon-carbon triple bonds; the same complex allows for the isolation of vinylgold intermediates. X= (C6F5)4B. CAAC = cyclic (alkyl) (amino)carbene.