121919-21-9

Basic information

• Product Name: 3-Methyl-2-oxo-4-vinyl-cyclohex-3-enecarboxylic acid ethyl ester
• Synonyms: 3-Methyl-2-oxo-4-vinyl-cyclohex-3-enecarboxylic acid ethyl ester
• CAS NO: 121919-21-9
• Molecular Weight: 208.257
• Mol File: 121919-21-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Methyl-2-oxo-4-vinyl-cyclohex-3-enecarboxylic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Methyl-2-oxo-4-vinyl-cyclohex-3-enecarboxylic acid ethyl ester(121919-21-9)
• EPA Substance Registry System: 3-Methyl-2-oxo-4-vinyl-cyclohex-3-enecarboxylic acid ethyl ester(121919-21-9)

Safety Data

• Hazardous Substances Data: 121919-21-9(Hazardous Substances Data)

Upstream product

• 98954-18-8 2-methyl-3-vinyl-cyclohex-2-enone 
• 541-41-3 chloroformic acid ethyl ester 
• 1193-55-1 2-methylcyclohexane-1,3-dione 
• 37457-15-1 3-isobutoxy-2-methyl-2-cyclohexen-1-one 

Downstream Products

• 121919-25-3 cis-/trans-6-<<(tert-butyldimethylsilyl)oxy>methyl>-2-methyl-3-vinyl-2-cyclohexen-1-ol 
• 121919-00-4 trans-6-<<(tert-butyldimethylsilyl)oxy>methyl>-2-methyl-1-(2-propynyloxy)-3-vinyl-2-cyclohexene 
• 121919-00-4 cis-6-<<(tert-butyldimethylsilyl)oxy>methyl>-2-methyl-1-(2-propynyloxy)-3-vinyl-2-cyclohexene 
• 121919-22-0 2-methyl-3-vinyl-cyclohexen-1-ol 
• 121919-23-1 cis-/trans-2-methyl-6-(hydroxymethyl)-3-vinyl-2-cyclohexen-1-ol 

Relevant articles and documents

Competitive Intramolecular Cycloaddition and Tandem Cycloaddition/-Sigmatropic Rearrangement Sequence of Allenyl 3-Vinyl-2-cyclohexenyl Ethers: Evidence for Switching of the Reaction Pathway by the Substituent Effects

The base-catalyzed intramolecular cycloaddition reactions (t-BuOK, t-BuOH, 83 deg C) of variously substituted propargyl 3-vinyl-2-cyclohexenyl ethers have been investigated.The reaction proceeded smoothly via the initial isomerization to the corresponding