121948-77-4 Usage
Description
N,N',N''-triisopropylguanidine, also known as N,N'',N''''-Tris(1-methylethyl)guanidine, is an organic compound with the chemical formula C10H22N4. It is a derivative of guanidine, featuring three isopropyl groups attached to the nitrogen atoms. N,N',N''-triisopropylguanidine is known for its potential applications in various fields due to its unique structural properties.
Uses
Used in Chemical Synthesis:
N,N',N''-triisopropylguanidine is used as an intermediate in the synthesis of trialkylguanidinato-supported zirconium complexes. Its unique structure allows for the formation of stable complexes with zirconium, which can be further utilized in various chemical reactions and applications.
Used in Structural Investigation:
N,N',N''-triisopropylguanidine is also used in the structural investigation of trialkylguanidinato-supported zirconium complexes. The study of these complexes can provide valuable insights into their properties, reactivity, and potential applications in various fields, such as catalysis, materials science, and pharmaceuticals.
Check Digit Verification of cas no
The CAS Registry Mumber 121948-77-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,1,9,4 and 8 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 121948-77:
(8*1)+(7*2)+(6*1)+(5*9)+(4*4)+(3*8)+(2*7)+(1*7)=134
134 % 10 = 4
So 121948-77-4 is a valid CAS Registry Number.
121948-77-4Relevant articles and documents
Titanacarborane mediated C-N bond forming/breaking reactions
Shen, Hao,Xie, Zuowei
scheme or table, p. 1652 - 1657 (2009/10/11)
Constrained-geometry titanacarboranes [σ:η1:η5-(OCH2)(R2NCH2)C2B9H9]Ti(NR2) (R = Me, Et) are synthesized via an unexpected reaction of [Me3NH][μ-7,8-CH2OCH2-7,8-C2B9H10] with Ti(NR2)4 (R = Me, Et), involving a C-O bond cleavage and C-N bond formation. These complexes can be readily converted to new amide species or alkoxide by reacting with amines or esters, respectively. Insertion of a series of unsaturated molecules into the Ti-N bond of the aforementioned complexes results in the formation of various half-sandwich titanacarboranes. [σ:η1:η5-(OCH2)(Me2NCH2)C2B9H9]Ti(NMe2) is also able to efficiently catalyze the hydroamination of carbodiimides and the transamination of guanidines. These results are summarized in this brief account.