122079-42-9

Basic information

• Product Name: 2(3H)-Furanone, dihydro-5-methoxy-4-(phenylthio)-, (4R,5R)-rel-
• CAS NO: 122079-42-9
• Molecular Formula: C11H12O3S
• Molecular Weight: 224.28
• Mol File: 122079-42-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2(3H)-Furanone, dihydro-5-methoxy-4-(phenylthio)-, (4R,5R)-rel-(CAS DataBase Reference)
• NIST Chemistry Reference: 2(3H)-Furanone, dihydro-5-methoxy-4-(phenylthio)-, (4R,5R)-rel-(122079-42-9)
• EPA Substance Registry System: 2(3H)-Furanone, dihydro-5-methoxy-4-(phenylthio)-, (4R,5R)-rel-(122079-42-9)

Safety Data

• Hazardous Substances Data: 122079-42-9(Hazardous Substances Data)

Upstream product

• 10449-66-8 5-methoxyfuran-2(5H)-one 
• 108-98-5 thiophenol 

Downstream Products

• 110211-09-1 2-phenylthiobutane-1,4-diol 

Relevant articles and documents

Efficient synthesis of vinyl and alkyl sulfides via hydrothiolation of alkynes and electron-deficient olefins using soluble and heterogenized gold complexes catalysts

Soluble and heterogenized gold complexes catalyze the hydrothiolation of alkynes and electron-deficient olefins in high yields and with high anti-Markovnikov selectivity. Moreover heterogenized catalysts could be recycled in several successive runs withou

ASYMMETRIC 1,4-ADDITIONS TO 5-ALKOXY-2(5H)-FURANONES. AN EFFICIENT SYNTHESIS OF (R)- AND (S)-3,4-EPOXY-1-BUTANOL

The synthesis of enantiomerically pure 5-menthyloxy-2(5H)-furanones is described as well as the diastereoselective 1,4-addition of thiols to these butenolides to yield new homochiral C4-synthons.Kinetic resolution of 5-methoxy-2(5H)-furanone, with an enantiomeric excess of 13percent, was achieved by cinchonidine catalysed thiophenol addition. The synthetic utility of the asymmetric thiol additions is illustrated in an efficient route to enantiomerically pure (R)- and (S)-3,4-epoxy-1-butanol.