122088-57-7Relevant articles and documents
Process for the minimization of racemization in the preparation of optically active ((aryloxy)phenoxy)propionate herbicides
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, (2008/06/13)
One of the routes to prepare optically active 2-(4-aryloxyphenoxy)propionic acid ester herbicide is to couple optically active 2-(4-hydrophenoxy)propionic acid esters with halogenated aromatic or heteroaromatic compounds. Conversion of the optically active 2-(4-hydroxyphenoxy)propionic acid ester into the acid salt prior to the coupling step effectively prevents the racemization that unexpectedly occurs otherwise.