122136-10-1

Basic information

• Product Name: n-octyl 1-phenylethyl ether
• Synonyms: n-octyl 1-phenylethyl ether
• CAS NO: 122136-10-1
• Molecular Weight: 234.382
• Mol File: 122136-10-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: n-octyl 1-phenylethyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: n-octyl 1-phenylethyl ether(122136-10-1)
• EPA Substance Registry System: n-octyl 1-phenylethyl ether(122136-10-1)

Safety Data

• Hazardous Substances Data: 122136-10-1(Hazardous Substances Data)

Upstream product

• 111-87-5 octanol 
• 98-85-1 1-Phenylethanol 
• 93-96-9 bis(1-phenylethyl)ether 
• 100-41-4 ethylbenzene 
• 94381-42-7 2,2-bis(1-octyloxy)propane 

Downstream Products

• 111-87-5 octanol 
• 124-07-2 Octanoic acid 

Relevant articles and documents

Molybdenum (VI)-catalyzed dehydrative construction of C[sbnd]O and C[sbnd]S bonds formation via etherification and thioetherification of alcohols and thiols

An inexpensive, easily available, environmentally benign, and efficient catalyst molybdenum(VI) dioxo (acetylacetonate)2 was used for the direct oxo- and thioetherification of alcohol. This method endures selective molybdenum catalyzed dehydrative synthesis of symmetrical ethers from benzylic secondary alcohols as well as unsymmetrical ethers from the reaction of benzylic secondary alcohols with primary alcohol. Furthermore, we have been also successful in the synthesis of Aryl thioether by using alcohol and thiols.

CATALYTIC C-H BOND ACTIVATION FOR THE SYNTHESIS OF ETHERS AND THIOETHERS

Disclosed is a method for the transition metal-mediated oxidation of C-H bonds to form C-0 or C-S bonds. The methods are useful for the formation of ethers (R-OR') from alcohols, R'OH, and sp3 -hybridized C-H bonds in substrates, R-H. Aryl or heteroaryl acetates may also be used for C-H to C-OAr bond formation. The methods are also useful in the preparation of C-S bonds from acetyl-protected thiols, MeC(0)SR, and disulfides, RSSR. Advantageously, the methods minimize reaction steps, the handling of oxidized intermediates, and environmental impact.

BiBr3, an efficient catalyst for the benzylation of alcohols: 2-Phenyl- 2-propyl, a new benzyl-type protecting group

The benzylation of aliphatic alcohols with various benzylic alcohols has been achieved in the presence of BiBr3 under mild conditions. 2- Phenylpropan-2-ol proved to be the most efficient and can be considered as a novel protecting group. (C) 2000 Elsevier Science Ltd.