122188-16-3

Basic information

• Product Name: Sn(tetra-m-tolylporphyrin)(ClO₄)2
• CAS NO: 122188-16-3
• Molecular Weight: 986.452
• Mol File: 122188-16-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Sn(tetra-m-tolylporphyrin)(ClO₄)2(CAS DataBase Reference)
• NIST Chemistry Reference: Sn(tetra-m-tolylporphyrin)(ClO₄)2(122188-16-3)
• EPA Substance Registry System: Sn(tetra-m-tolylporphyrin)(ClO₄)2(122188-16-3)

Safety Data

• Hazardous Substances Data: 122188-16-3(Hazardous Substances Data)

Upstream product

• 104717-09-1 dichloro(5,10,15,20-tetra-m-tolylporphyrinato)tin(IV) 

Downstream Products

• 14797-73-0 perchlorate^(1-) 

Relevant articles and documents

Effect of Axially Bound Anions on the Electroreduction of Tin(IV) Porphyrins in Tetrahydrofuran

The spectroscopic characterization and electrochemistry of SnL(X)2 is presented where L is the dianion of tetra-p-tolylporphyrin or tetra-m-tolylporphyrin and X is CIO4-, Br-, Cl-, F-, or OH-.In all cases, electroreduction leads to porphyrin ? anion radicals and dianions which were characterized in tetrahydrofuran by spectroelectrochemistry and e.s.r. spectroscopy.Dissociation of one CIO4- ion from SnL(CIO4)2 occurs before electroreduction of the complex but no dissociation is observed either before or after electroreduction of SnL(F)2 or SnL(OH)2.In contrast, one Br- ion dissociates after the first electron addition to SnL(Br)2 while one Cl- ion dissociates from SnCl(Cl)2 after the second electroreduction of this complex.