1222085-71-3

Basic information

• Product Name: (E)-1-phenylhept-2-en-1-yl acetate
• Synonyms: (E)-1-phenylhept-2-en-1-yl acetate
• CAS NO: 1222085-71-3
• Molecular Weight: 232.323
• Mol File: 1222085-71-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-phenylhept-2-en-1-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-phenylhept-2-en-1-yl acetate(1222085-71-3)
• EPA Substance Registry System: (E)-1-phenylhept-2-en-1-yl acetate(1222085-71-3)

Safety Data

• Hazardous Substances Data: 1222085-71-3(Hazardous Substances Data)

Upstream product

• 13154-16-0 trans-hex-1-enylmagnesium bromide 
• 100-52-7 benzaldehyde 
• 140148-19-2 (2E)-1-phenylhept-2-en-1-ol 
• 75-36-5 acetyl chloride 
• 18829-55-5 (E)-2-Heptenal 
• 108-86-1 bromobenzene 

Downstream Products

• 1222085-73-5 C₁₈H₂₄O₄ 
• 1222085-72-4 (E)-dimethyl 2-(1-phenylhept-1-en-3-yl)malonate 

Relevant articles and documents

Size-Exclusion Borane-Catalyzed Domino 1,3-Allylic/Reductive Ireland–Claisen Rearrangements: Impact of the Electronic and Structural Parameters on the 1,3-Allylic Shift Aptitude

The reductive Ireland–Claisen rearrangement through borane-mediated hydrosilylation is reported. The method employs a borane catalyst with a special structural design and affords access to synthetically relevant products with high diastereoselectivity. Depending on electronic and structural parameters, the reaction can be coupled with a 1,3-allylic shift, thus the valence isomer of the Ireland–Claisen product is formed.