122227-21-8

Basic information

• Product Name: Ru₃(CO)11(DPPA)
• CAS NO: 122227-21-8
• Molecular Weight: 1005.72
• Mol File: 122227-21-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ru₃(CO)11(DPPA)(CAS DataBase Reference)
• NIST Chemistry Reference: Ru₃(CO)11(DPPA)(122227-21-8)
• EPA Substance Registry System: Ru₃(CO)11(DPPA)(122227-21-8)

Safety Data

• Hazardous Substances Data: 122227-21-8(Hazardous Substances Data)

Upstream product

• 15243-33-1 dodecacarbonyl-triangulo-triruthenium 
• 1184-78-7 trimethylamine-N-oxide 
• 5112-95-8 bis(diphenylphosphino)acetylene 

Relevant articles and documents

Bis(diphenylphosphino)acetylene as a bridging ligand between homo- and hetero-metallic clusters

The reactions of Ru3(CO)11L, HRu3(CO)8(C2But)L (L=DPPA, CH3CN) with (η5-C5H5)NiM3(μ-H)3(CO)8L (M=Ru, Os; L=DPPA, CH3CN) lead to cluster interlinked derivatives, with DPPA acting as a bridge (DPPA=bis(diphenylphosphino)acetylene).The complexes have been identified by elemental analyses and spectroscopy.Side reactions, such as displacement of ligands or thermal disproportionation, have been observed.