1226600-23-2

Basic information

• Product Name: (Z)-1-chloro-4-(2,3,3,3-tetrafluoroprop-1-en-1-yl)benzene
• Synonyms: (Z)-1-chloro-4-(2,3,3,3-tetrafluoroprop-1-en-1-yl)benzene
• CAS NO: 1226600-23-2
• Molecular Weight: 224.585
• Mol File: 1226600-23-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (Z)-1-chloro-4-(2,3,3,3-tetrafluoroprop-1-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-chloro-4-(2,3,3,3-tetrafluoroprop-1-en-1-yl)benzene(1226600-23-2)
• EPA Substance Registry System: (Z)-1-chloro-4-(2,3,3,3-tetrafluoroprop-1-en-1-yl)benzene(1226600-23-2)

Safety Data

• Hazardous Substances Data: 1226600-23-2(Hazardous Substances Data)

Upstream product

• 754-12-1 2,3,3,3-tetrafluoro-propene 
• 1679-18-1 4-Chlorophenylboronic acid 
• 212619-47-1 (Z)-2-fluoro-2-trifluoromethylethenyl tosylate 
• 27336-23-8 1,1-dibromo-1,2,2,2-tetrafluoroethane 
• 52372-80-2 (4-chlorobenzylidene)hydrazine 

Relevant articles and documents

Nanopalladium-Catalyzed Oxidative Heck Reaction of Fluorinated Olefins: H2O2 as a Green Oxidant

Pd-based nanocatalysts were prepared through immobilization of Pd(OAc)2/phenanthroline on nanocarbon materials and subsequent pyrolysis. The catalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electron microscopy (TEM). Pd-based nanocatalysts can efficiently catalyze the oxidative Heck reaction of tetrafluoropropylene by using H2O2 as a green oxidant and generate (Z)-β-fluoro-β-(trifluoromethyl)styrenes in excellent yield. The yield and Z/E selectivity of the titled reaction remained higher than 90% after four reaction cycles. Graphic Abstract: [Figure not available: see fulltext.]

Oxidative Heck Reaction of Fluorinated Olefins with Arylboronic Acids by Palladium Catalysis

The palladium-catalyzed oxidative Heck reaction of 2,3,3,3-tetrafluoroprop-1-ene with various arylboronic acids was explored for the first time. This method provides a direct route to access (Z)-β-fluoro-β-(trifluoromethyl)styrenes with high stereoselectivity.