1226911-82-5

Basic information

• Product Name: 1-(4-methyl-phenyl)-2-methylallyl alcohol
• Synonyms: 1-(4-methyl-phenyl)-2-methylallyl alcohol
• CAS NO: 1226911-82-5
• Molecular Weight: 162.232
• Mol File: 1226911-82-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(4-methyl-phenyl)-2-methylallyl alcohol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-methyl-phenyl)-2-methylallyl alcohol(1226911-82-5)
• EPA Substance Registry System: 1-(4-methyl-phenyl)-2-methylallyl alcohol(1226911-82-5)

Safety Data

• Hazardous Substances Data: 1226911-82-5(Hazardous Substances Data)

Upstream product

• 13291-18-4 isopropenylmagnesium bromide 
• 104-87-0 4-methyl-benzaldehyde 
• 25574-04-3 1-p-tolyl-1-propanol 
• 5337-93-9 4'-methylpropiophenone 
• 62834-89-3 2-methyl-1-(p-tolyl)prop-2-en-1-one 
• 106-38-7 para-bromotoluene 

Downstream Products

• 1450897-69-4 (E)-triisopropyl(4-methyl-5-phenylpent-4-en-1-yn-1-yl)silane 
• 1226911-71-2 (E)-4-methyl-5-p-tolylpent-4-enenitrile 
• 1226911-52-9 2-Ethyl-4-methyl-5-(4-methylphenyl)-4-pentenal 
• 1226911-84-7 (E)-4-methyl-5-(p-tolyl)pent-4-en-1-ol 
• 1226911-69-8 (E)-4-methyl-5-(p-tolyl)pent-4-enal 
• 1226911-57-4 methyl (4E)-4-methyl-5-(4-methylphenyl)-4-pentenoate 
• 557-40-4 Allyl ether 

Relevant articles and documents

Iron(III) Chloride/Phenylsilane-Mediated Cascade Reaction of Allyl Alcohols with Maleimides: Synthesis of Poly-Substituted γ-Butyrolactones

A iron-catalyzed free radical cascade reaction of allyl alcohols with N-substituted maleimides for accessing poly-substituted γ-butyrolactones has been developed. In this protocol, various allyl alcohols can open N-substituted maleimide rings to form allyl ester intermediates, and the allyl ester intermediates can be converted into an allyl ester alkyl radicals and undergo intramolecular free radical addition cyclization to form a polysubstituted γ-butyrolactones. In this protocol, spiro γ-butyrolactone compounds can be also synthesized. Meanwhile, the strategy could be applied to further construct a fully substituted tetrahydrofuran. The reaction is not sensitive to oxygen or moisture and has been performed on gram-scale. (Figure presented.).