122760-43-4Relevant articles and documents
Transition metal heterocyclic chemistry. IX. An α-selenoketoketene. Trapping subsequent to oxidative release from tricarbonyliron complexes to form vinyl selenides
Pannell, Keith H.,Mayr, Armin J.,Carrasco-Flores, Benjamin
, p. 97 - 102 (1988)
Treatment of α-selenoketocyclohexylene-Fe2(CO)6 (1) and the related α-selenoketoketene complex (2) with trimethylamine oxide leads to the formation of a transient α-selenoketoketene, a previously unknown species.The transient species may be trapped by alcohols to produce esters of bis(2-carboxy-1-cyclohexenyl)diselenide, examples of vinylselenides.Reductive elimination of selenium from these esters using Raney Nickel leads to the formation of the cyclohexane carboxylate esters.