1228183-94-5

Basic information

• Product Name: Ni(η2-ethyl cyclopropylideneacetate)(P(C6H11)3)2
• Synonyms: Ni(η2-ethyl cyclopropylideneacetate)(P(C6H11)3)2
• CAS NO: 1228183-94-5
• Molecular Weight: 745.713
• Mol File: 1228183-94-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ni(η2-ethyl cyclopropylideneacetate)(P(C6H11)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: Ni(η2-ethyl cyclopropylideneacetate)(P(C6H11)3)2(1228183-94-5)
• EPA Substance Registry System: Ni(η2-ethyl cyclopropylideneacetate)(P(C6H11)3)2(1228183-94-5)

Safety Data

• Hazardous Substances Data: 1228183-94-5(Hazardous Substances Data)

Upstream product

• 1295-35-8 bis(1,5-cyclooctadiene)nickel ⁽⁰⁾ 
• 74592-36-2 ethyl cyclopropenylideneacetate 
• 2622-14-2 tricyclohexylphosphine 

Downstream Products

• 1295-35-8 bis(1,5-cyclooctadiene)nickel ⁽⁰⁾ 
• 1228183-95-6 Ni(C₈H₁₂)((E,E)-1,2-bis(exo-CHCOOEt)cyclohexane) 

Relevant articles and documents

[3+3] cyclodimerization of methylenecyclopropanes: Stoichiometric and catalytic reactions of Nickel(0) with electron-deficient alkylidenecyclopropanes

Stoichiometric treatment of Ni(cod)2 with ethyl cyclopropylideneacetate (ECPA) in the presence of PCy3 resulted in an unpredicted formation of a Ni(0) complex bearing an (E,E)-1,2-bis(exo- alkylidene)cyclohexane ligand, which stemmed from the [3 + 3] cyclodimerization of ECPA. The reaction could be expanded to a Ni(0)-catalyzed [3 + 3] cyclodimerization reaction of ester-substituted methylenecyclopropanes, giving the corresponding cyclohexane derivatives in excellent yields.