1229574-65-5

Basic information

• Product Name: [bis(naphth-1,8-diyl-8-oxy)phosphoranide](P(OPh)3)2 platinum(II)Cl
• CAS NO: 1229574-65-5
• Molecular Weight: 1166.4
• Mol File: 1229574-65-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [bis(naphth-1,8-diyl-8-oxy)phosphoranide](P(OPh)3)2 platinum(II)Cl(CAS DataBase Reference)
• NIST Chemistry Reference: [bis(naphth-1,8-diyl-8-oxy)phosphoranide](P(OPh)3)2 platinum(II)Cl(1229574-65-5)
• EPA Substance Registry System: [bis(naphth-1,8-diyl-8-oxy)phosphoranide](P(OPh)3)2 platinum(II)Cl(1229574-65-5)

Safety Data

• Hazardous Substances Data: 1229574-65-5(Hazardous Substances Data)

Upstream product

• 101-02-0 triphenyl phosphite 
• 30053-58-8 cis-[PtCl₂(triphenyl phosphite)2] 

Relevant articles and documents

Syntheses and characterization of novel bis(phosphoranido)platinum(II) complexes: Reactions of lithium bis(naphth-l,8-diyl-8-oxy)phosphoranide with cis-PtCl2(PRs)2 (R = OPh, OMe, Me)

The reactions of cis-PtCl2(PR3J2 (R = OPh, OMe) with 1 equiv. of lithium, phosphoranide generated from, a bis(naphth-1,8diyl-8-oxy)phosphorane lead to the formation of cis-monophosphoranido complexes with high stereospecificity. The reaction of cis-PtCl2(PMe3)2 with 1 equiv. of the lithium, phosphoranide afforded a trans-monophosphoranido complex, exclusively. Hitherto unknown trans-bis(phosphoranido)platinum.(II) complexes were obtained as major products in the reactions of cis-PtCl2(PR3)2 (R = OPh, OMe, Me) with an excess of the lithium phosphoranide. The stereochemistry was confirmed by X-ray structural analysis of the bis(phosphoranido) complex bearing triphenyl phosphites.