122977-68-8

Basic information

• Product Name: trifluoro-1,1,1 phenyl-6 trimethylsilyloxy-2 heptadiene-2,6
• Synonyms: trifluoro-1,1,1 phenyl-6 trimethylsilyloxy-2 heptadiene-2,6
• CAS NO: 122977-68-8
• Molecular Weight: 314.423
• Mol File: 122977-68-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trifluoro-1,1,1 phenyl-6 trimethylsilyloxy-2 heptadiene-2,6(CAS DataBase Reference)
• NIST Chemistry Reference: trifluoro-1,1,1 phenyl-6 trimethylsilyloxy-2 heptadiene-2,6(122977-68-8)
• EPA Substance Registry System: trifluoro-1,1,1 phenyl-6 trimethylsilyloxy-2 heptadiene-2,6(122977-68-8)

Safety Data

• Hazardous Substances Data: 122977-68-8(Hazardous Substances Data)

Upstream product

• 400-53-3 trimethylsilyl trifluoroacetate 

Downstream Products

• 122977-74-6 1,1,1-Trifluoro-6-phenyl-hept-6-en-2-one 

Relevant articles and documents

NOUVELLE SYNTHESE DE TRIFLUOROMETHYLCETONES ET D' α-BROMO TRIFLUOROMETHYLCETONES

We report a new method for the preparation of trifluoromethylketones, as an alternative to the use of organometallics.The condensation of phosphonium ylides with trimethylsilyl trifluoroacetate provides silyloxy enol ethers whose hydrolysis leads to trifluoromethylketones.Bromation of the same silyloxy enol ether is also a convenient preparation of α-bromo trifluoromethylketone.