123171-52-8Relevant articles and documents
A facile route to 20-hydroxyecdysone and side chain homologues from poststeron
Hedtmann, Udo,Klintz, Ralf,Hobert, Kurt,Frelek, Jadwiga,Vlahov, Iontscho,Welzel, Peter
, p. 3753 - 3772 (2007/12/18)
A flexible approach to ecdysteroids, chain elongated at C-26 and C-27, is reported. Key features are the addition of 5-lithio 2,3-dihydrofurans (3) to poststeron (10) and a stereoselective reduction of the 22-∞ group.