1231948-43-8Relevant articles and documents
Aggregation-Induced Emission of Platinum(II) Metallacycles and Their Ability to Detect Nitroaromatics
Chowdhury, Aniket,Howlader, Prodip,Mukherjee, Partha Sarathi
, p. 7468 - 7478 (2016)
Two new acceptors containing platinum-carbazole (1) and platinum-triphenylamine (2) backbones with bite angles of 90° and 120°, respectively, have been synthesised and characterised. Reactions of the rigid acceptor 1 with linear dipyridyl-based donors (3 and 4) generated [4+4] self-assembled molecular squares (5 and 6), and similar treatments with acceptor 2 instead of 1 yielded [6+6] self-assembled molecular hexagons (7 and 8). The metallacycles were characterised by multinuclear NMR spectroscopy (1H and 31P) and ESI-MS. The geometries of the metallacycles were optimised by using the PM6 method. When aggregates of the metallacycles were formed by adding hexane solutions in dichloromethane, aggregation-induced emission was observed for metallacycles 5 and 7, and aggregation-caused quenching was observed for metallacycles 6 and 8. The formation of aggregates was verified by dynamic light scattering and TEM analyses. Macrocycles 5 and 7 are white-light emitters in THF. Moreover, their high luminescence in both solution and the solid state was utilised for the recognition of nitroaromatic explosives.
Multistep oxidation of diethynyl oligophenylamine-bridged diruthenium and diiron complexes
Zhang, Jing,Guo, Shen-Zhen,Dong, Yu-Bao,Rao, Li,Yin, Jun,Yu, Guang-Ao,Hartl, Franti?ek,Liu, Sheng Hua
, p. 1001 - 1015 (2017)
Homo-dinuclear nonlinear complexes [{M(dppe)-Cp?}2{μ-(-C=C)2X}] (dppe = 1,2-bis(diphenylphosphino) ethane; Cp? = η5-C5Me5; X = triphenylamine (TPA), M = Ru (1a) and Fe (1b); X =
Synthesis, photophysical, electrochemical, and DSSC application of novel donor-acceptor triazole bridged dendrimers with a triphenylamine core and benzoheterazole as a surface unit
Rajavelu, Kannan,Rajakumar, Perumal,Sudip, Mandal,Kothandaraman, Ramanujam
, p. 10246 - 10258 (2016)
Triazole bridged novel donor-acceptor dendrimers with triphenylamine as the core and benzoheterazole as the surface unit have been synthesized by click chemistry via a convergent approach. All the dendrimers exhibited excellent optical and electrochemical