123316-16-5

Basic information

• Product Name: 8-methyl-7-phenyl-1,2,4,5,6-pentafluoro-3-aza-bicyclo<4.2.0>octa-2,4,7-triene
• CAS NO: 123316-16-5
• Molecular Weight: 285.216
• Mol File: 123316-16-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 8-methyl-7-phenyl-1,2,4,5,6-pentafluoro-3-aza-bicyclo<4.2.0>octa-2,4,7-triene(CAS DataBase Reference)
• NIST Chemistry Reference: 8-methyl-7-phenyl-1,2,4,5,6-pentafluoro-3-aza-bicyclo<4.2.0>octa-2,4,7-triene(123316-16-5)
• EPA Substance Registry System: 8-methyl-7-phenyl-1,2,4,5,6-pentafluoro-3-aza-bicyclo<4.2.0>octa-2,4,7-triene(123316-16-5)

Safety Data

• Hazardous Substances Data: 123316-16-5(Hazardous Substances Data)

Upstream product

• 673-32-5 1-Phenylprop-1-yne 
• 700-16-3 Pentafluoropyridine 

Relevant articles and documents

REGIOSPECIFIC 2+2 PHOTOADDITION OF PHENYL SUBSTITUTED ACETYLENES TO PENTAFLUOROPYRIDINE

Irradiation of a cyclohexane solution of pentafluoropyridine and 1-phenyl-2-alkyl-acetylenes produced regiospecific 2+2 photocycloaddition, thus forming 3-aza-bicyclo octa-2,4,7-triene derivatives, which further phototransformed to 7-aza-tricyclo2,5>octa-3,7-diene derivatives.Further phototransformation of the tricyclic system depended on the alkyl substituent: in the case of tert-butyl, 1,2,5,6,7-pentafluoro-3-tert-butyl-4-phenyl-8-aza-bicycloocta-2,4,7-triene was formed, while in the case of a methyl substituent, 1-methyl-2,3,5,6,7-pentafluoro-8-phenyl-4-aza cycloocta-1,3,5,7-tetraene resulted.