1233875-87-0

Basic information

• Product Name: α-bromo-4,5-dimethoxy-2-nitrophenylacetic acid allyl ester
• Synonyms: α-bromo-4,5-dimethoxy-2-nitrophenylacetic acid allyl ester
• CAS NO: 1233875-87-0
• Molecular Weight: 360.161
• Mol File: 1233875-87-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: α-bromo-4,5-dimethoxy-2-nitrophenylacetic acid allyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: α-bromo-4,5-dimethoxy-2-nitrophenylacetic acid allyl ester(1233875-87-0)
• EPA Substance Registry System: α-bromo-4,5-dimethoxy-2-nitrophenylacetic acid allyl ester(1233875-87-0)

Safety Data

• Hazardous Substances Data: 1233875-87-0(Hazardous Substances Data)

Upstream product

• 1233875-86-9 α-diazo-4,5-dimethoxy-2-nitrophenylacetic acid allyl ester 

Downstream Products

• 1233875-96-1 acetic acid α-allyloxycarbonyl-4,5-dimethoxy-2-nitrobenzyl ester 
• 1233876-01-1 penicillin G α-allyloxycarbonyl-4,5-dimethoxy-2-nitrobenzyl ester 
• 1233875-98-3 propanoic acid α-allyloxycarbonyl-4,5-dimethoxy-2-nitrobenzyl ester 
• 1233876-00-0 benzoic acid α-allyloxycarbonyl-4,5-dimethoxy-2-nitrobenzyl ester 
• 1233875-99-4 hexanoic acid α-allyloxycarbonyl-4,5-dimethoxy-2-nitrobenzyl ester 
• 1373931-86-2 (2S)-t-butyl 3-(4-(2-(allyloxy)-1-(4,5-dimethoxy-2-nitrophenyl)-2-oxoethoxy)phenyl)-2-((t-butoxycarbonyl)amino)propanoate 
• 1373931-75-9 (2S)-methyl 3-(4-(2-(allyloxy)-1-(4,5-dimethoxy-2-nitrophenyl)-2-oxoethoxy)phenyl)-2-((t-butoxycarbonyl)amino)propanoate 
• 1373931-74-8 allyl 2-(4-(t-butyl)phenoxy)-2-(4,5-dimethoxy-2-nitrophenyl)acetate 
• 1373931-78-2 (1S)-1-carboxy-2-(4-(carboxy(4,5-dimethoxy-2-nitrophenyl)methoxy)phenyl)ethanaminium 2,2,2-trifluoroacetate 
• 1373931-76-0 2-(4-(t-butyl)phenoxy)-2-(4,5-dimethoxy-2-nitrophenyl)acetic acid 
• 1373931-88-4 (2S)-2-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)-3-(4-(2-(allyloxy)-1-(4,5-dimethoxy-2-nitrophenyl)-2-oxoethoxy)phenyl)propanoic acid 
• 1373931-94-2 (1S)-2-(4-(2-(allyloxy)-1-(4,5-dimethoxy-2-nitrophenyl)-2-oxoethoxy)phenyl)-1-carboxyethanaminium 2,2,2-trifluoroacetate 

Relevant articles and documents

α-Carboxy-6-nitroveratryl: A photolabile protecting group for carboxylic acids

(Figure presented) The synthesis of a new photolabile protecting group for carboxylic acids, α-carboxy-6-nitroveratryl (αCNV), is described. Bromide 3, prepared in four steps from 3,4-dimethoxyphenylacetic acid, was used to alkylate carboxylic acids under mild conditions in good yield. Palladium-catalyzed deallylation afforded the acids 4a-h, which underwent rapid and quantitative photolysis at wavelengths longer than 300 nm to liberate the carboxylic acid in good to quantitative yield. The rate of photolysis and quantum yield were determined to be 325 s-1 and 0.17.