123433-61-4

Basic information

• Product Name: 2-Oxetanone, 4-[3-(phenylmethoxy)propyl]-3-(trimethylsilyl)-
• CAS NO: 123433-61-4
• Molecular Formula: C16H24O3Si
• Molecular Weight: 292.45
• Mol File: 123433-61-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Oxetanone, 4-[3-(phenylmethoxy)propyl]-3-(trimethylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Oxetanone, 4-[3-(phenylmethoxy)propyl]-3-(trimethylsilyl)-(123433-61-4)
• EPA Substance Registry System: 2-Oxetanone, 4-[3-(phenylmethoxy)propyl]-3-(trimethylsilyl)-(123433-61-4)

Safety Data

• Hazardous Substances Data: 123433-61-4(Hazardous Substances Data)

Upstream product

• 4071-85-6 trimetylsilylketene 
• 5470-84-8 4-benzyloxybutanal 

Downstream Products

• 123433-58-9 (Tetrahydro-furan-2-yl)-acetic acid benzyl ester 
• 2434-00-6 (tetrahydro-furan-2-yl)-acetic acid 
• 33606-34-7 (2-(tetrahydro-furan-2-yl)-ethanol) 
• 139609-09-9 threo-4-<3-(benzyloxy)propyl>-3-(ethylhydroxymethyl)-2-oxetanone 
• 139609-09-9 erythro-4-<3-(benzyloxy)propyl>-3-(ethylhydroxymethyl)-2-oxetanone 
• 123433-56-7 4-(3-Benzyloxy-propyl)-oxetan-2-one 
• 126502-90-7 (3S,4S)-4-(3-Benzyloxy-propyl)-3-methyl-oxetan-2-one 
• 126502-90-7 (3R,4S)-4-(3-Benzyloxy-propyl)-3-methyl-oxetan-2-one 
• 126502-90-7 4-(3-Benzyloxy-propyl)-3-methyl-oxetan-2-one 

Relevant articles and documents

Studies of the asymmetric [2+2] cycloaddition of silylketenes and aldehydes employing Ti-TADDOL catalysts

Ti-TADDOL catalysts provide good reactivity and moderate enantioselectivity in the asymmetric [2+2] cycloaddition of silyl ketenes and aldehydes. The effects of potential bidentate chelation of benzyloxy substituted aldehydes and of the steric size of the ketene silyl group were studied.

SYSTHESIS AND INTRAMOLECULAR RING CLEAVAGE OF 2-OXETANONES

Intermolecular 2+2 aldehyde-ketene cycloaddition, followed by Lewis acid induced intramolecular ring opening of the 2-oxetanone product have been used to prepare tetrahydrofuran and tetrahydropyran ring systems.