1235457-92-7

Basic information

• Product Name: ((2S,3S)-2-ethyl-3-propyloxiran-2-yl)methanol
• CAS NO: 1235457-92-7
• Molecular Weight: 144.214
• Mol File: 1235457-92-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ((2S,3S)-2-ethyl-3-propyloxiran-2-yl)methanol(CAS DataBase Reference)
• NIST Chemistry Reference: ((2S,3S)-2-ethyl-3-propyloxiran-2-yl)methanol(1235457-92-7)
• EPA Substance Registry System: ((2S,3S)-2-ethyl-3-propyloxiran-2-yl)methanol(1235457-92-7)

Safety Data

• Hazardous Substances Data: 1235457-92-7(Hazardous Substances Data)

Upstream product

• 1235457-83-6 (2R,3S)-2-ethyl-3-propyloxirane-2-carbaldehyde 
• 64344-45-2 (E)-2-ethyl-2-hexenal 
• 90112-78-0 2-ethyl-3-propyloxirane-2-carbaldehyde 

Relevant articles and documents

The cinchona primary amine-catalyzed asymmetric epoxidation and hydroperoxidation of α,β-unsaturated carbonyl compounds with hydrogen peroxide

Using cinchona alkaloid-derived primary amines as catalysts and aqueous hydrogen peroxide as the oxidant, we have developed highly enantioselective Weitz-Scheffer-type epoxidation and hydroperoxidation reactions of α,β-unsaturated carbonyl compounds (up to 99.5:0.5 er). In this article, we present our full studies on this family of reactions, employing acyclic enones, 5-15-membered cyclic enones, and α-branched enals as substrates. In addition to an expanded scope, synthetic applications of the products are presented. We also report detailed mechanistic investigations of the catalytic intermediates, structure-activity relationships of the cinchona amine catalyst, and rationalization of the absolute stereoselectivity by NMR spectroscopic studies and DFT calculations.