123707-26-6Relevant articles and documents
Use of N,N'-Dimethoxy-N,N'-dimethylurea as a Carbonyl Dication Equivalent in Organometallic Addition Reactions. Synthesis of Unsymmetrical Ketones
Whipple, Wesley L.,Reich, Hans J.
, p. 2911 - 2912 (1991)
-
TANDEM ORGANOMETALLIC ADDITION REACTIONS TO N-METHOXY-UREAS AND URETHANES IN THE PREPARATION OF UNSYMMETRICAL AND SYMMETRICAL KETONES
Hlasta, Dennis J.,Court, John J.
, p. 1773 - 1776 (2007/10/02)
The use of novel reagents 1a-c for the synthesis of ketones in a one pot reaction is described.An interesting leaving group effect was discovered in the fragmentation of the proposed complexes 2 to the intermediate N-methoxyamides 3.