1237512-14-9

Basic information

• Product Name: trimethyl((3-methyl-2-phenylbut-2-yl)peroxy)silane
• Synonyms: trimethyl((3-methyl-2-phenylbut-2-yl)peroxy)silane
• CAS NO: 1237512-14-9
• Molecular Weight: 252.429
• Mol File: 1237512-14-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trimethyl((3-methyl-2-phenylbut-2-yl)peroxy)silane(CAS DataBase Reference)
• NIST Chemistry Reference: trimethyl((3-methyl-2-phenylbut-2-yl)peroxy)silane(1237512-14-9)
• EPA Substance Registry System: trimethyl((3-methyl-2-phenylbut-2-yl)peroxy)silane(1237512-14-9)

Safety Data

• Hazardous Substances Data: 1237512-14-9(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 62837-59-6 1,2-dimethyl-1-phenyl-1-propanol 
• 42238-03-9 (+/-)-3-methyl-2-phenylbut-2-yl hydroperoxide 

Downstream Products

• 1237512-17-2 C₁₄H₂₄OSi 
• 62837-59-6 1,2-dimethyl-1-phenyl-1-propanol 
• 5440-69-7 N-isopropylbenzamide 
• 6967-88-0 1-bromo-4-isopropoxybenzene 

Relevant articles and documents

Alkylsilyl Peroxides as Alkylating Agents in the Copper-Catalyzed Selective Mono-N-Alkylation of Primary Amides and Arylamines

The copper-catalyzed selective mono-N-alkylation of primary amides or arylamines using alkylsilyl peroxides as alkylating agents is reported. The reaction proceeds under mild reaction conditions and exhibits a broad substrate scope with respect to the alkylsilyl peroxides, as well as to the primary amides and arylamines. Mechanistic studies suggest that the present reaction should proceed through a free-radical process that includes alkyl radicals generated from the alkylsilyl peroxides.