1238735-10-8

Basic information

• Product Name: 5,6-dihydro-6-t-butoxycarbonylmethyl-7-methylphenanthridine
• Synonyms: 5,6-dihydro-6-t-butoxycarbonylmethyl-7-methylphenanthridine
• CAS NO: 1238735-10-8
• Molecular Weight: 309.408
• Mol File: 1238735-10-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5,6-dihydro-6-t-butoxycarbonylmethyl-7-methylphenanthridine(CAS DataBase Reference)
• NIST Chemistry Reference: 5,6-dihydro-6-t-butoxycarbonylmethyl-7-methylphenanthridine(1238735-10-8)
• EPA Substance Registry System: 5,6-dihydro-6-t-butoxycarbonylmethyl-7-methylphenanthridine(1238735-10-8)

Safety Data

• Hazardous Substances Data: 1238735-10-8(Hazardous Substances Data)

Upstream product

• 615-37-2 ortho-methylphenyl iodide 
• 1663-39-4 tert-Butyl acrylate 
• 2727-71-1 N-(2-bromophenyl)-2,2,2-trifluoroacetamide 

Relevant articles and documents

One-pot palladium-catalyzed synthesis of selectively substituted phenanthridines by sequential aryl-aryl and heck couplings, aza-michael and retro-mannich reactions

A catalytic synthesis of selectively substituted phenanthridines is achieved through a reaction sequence involving palladium/norbornene-catalyzed unsymmetrical aryl-aryl and Heck couplings followed by aza-Michael and retro-Mannich reactions. In spite of the many steps involved the method is very simple and allows the formation of selectively substituted phenanthridines under mild conditions in a straightforward one-pot reaction starting from readily available aryl iodides and bromides.