124050-39-1

Basic information

• Product Name: diethyl (1-fluoro-2-oxopropyl)phosphonate
• Synonyms: diethyl (1-fluoro-2-oxopropyl)phosphonate
• CAS NO: 124050-39-1
• Molecular Weight: 212.158
• Mol File: 124050-39-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: diethyl (1-fluoro-2-oxopropyl)phosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl (1-fluoro-2-oxopropyl)phosphonate(124050-39-1)
• EPA Substance Registry System: diethyl (1-fluoro-2-oxopropyl)phosphonate(124050-39-1)

Safety Data

• Hazardous Substances Data: 124050-39-1(Hazardous Substances Data)

Upstream product

• 146036-63-7 2-(diethoxyphosphinyl)-2-fluoro-acetic acid chloride 
• 917-54-4 methyllithium 

Relevant articles and documents

A general and efficient synthesis of β-ketophosphonates

The acylation of organocuprates or organolithiated reagents with 2-dialkylphosphonoalkanoyl chlorides or dialkylphosphonofluoroacetyl chlorides represents a general and efficient route to β-ketophosphonates.A Horner reaction between the lithiated anions derived from α-fluoro-β-ketophosphonates and aldehydes leads to 2-fluoro-2-enones whereas the lithiated anions derived from γ-acetylenic-β-ketophosphonates afford enynones. β-ketophosphonate / 2-dialkylphosphonoalkanoyl chloride / dialkylphosphonofluoroacetyl chloride / 2-fluoro-2-enone / enynone