124070-06-0Relevant articles and documents
Copper-Catalysed (Diacetoxyiodo)benzene-Promoted Aerobic Esterification Reaction: Synthesis of Oxamates from Acetoacetamides
Zhang, Zhiguo,Gao, Xiaolong,Yu, Haifeng,Zhang, Guisheng,Liu, Jianming
, p. 3406 - 3411 (2018/07/31)
A copper-catalysed (diacetoxyiodo)benzene-promoted aerobic esterification reaction of acetoacetamides was developed for the synthesis of oxamates, which are useful precursors in synthetic organic chemistry. This practical and mild synthetic approach proceeded at 25 °C under open-air conditions and afforded methyl 2-oxo-2-(phenylamino)acetates in good to excellent yields combined with C?C σ-bond cleavage and formal oxidative C?H bond functionalization. A mechanism is proposed. (Figure presented.).
Hypervalent iodine(III)-induced methylene acetoxylation of 3-oxo-n-substituted butanamides
Liu, Wei-Bing,Chen, Cui,Zhang, Qing,Zhu, Zhi-Bo
supporting information; experimental part, p. 1436 - 1440 (2011/12/02)
1-Carbamoyl-2-oxopropyl acetate derivatives were synthesized through an acetoxylation process to methylene with the aid of (diacetoxyiodo)benzene (DIB) as the oxidant. Not only mild reaction conditions, but also excellent yields and good substrate scope m
Preparation of 3-Acetyl-2-hydroxyindoles via Rhodium Carbenoid Aromatic C-H Insertion
Etkin, Nola,Babu, Suresh D.,Fooks, Catherine J.,Durst, Tony
, p. 1093 - 1096 (2007/10/02)
-
