1242030-69-8

Basic information

• Product Name: (2-(2,6-dimethoxyphenyl)ethynyl)trimethylsilane
• Synonyms: (2-(2,6-dimethoxyphenyl)ethynyl)trimethylsilane
• CAS NO: 1242030-69-8
• Molecular Weight: 234.37
• Mol File: 1242030-69-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2-(2,6-dimethoxyphenyl)ethynyl)trimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (2-(2,6-dimethoxyphenyl)ethynyl)trimethylsilane(1242030-69-8)
• EPA Substance Registry System: (2-(2,6-dimethoxyphenyl)ethynyl)trimethylsilane(1242030-69-8)

Safety Data

• Hazardous Substances Data: 1242030-69-8(Hazardous Substances Data)

Usage

Description

(2-(2,6-dimethoxyphenyl)ethynyl)trimethylsilane is a chemical compound with the molecular formula C14H18O2Si. It is a silane compound that contains a triple bond between a carbon and a silicon atom and a substituted phenyl group. This chemical is commonly used as a precursor in the synthesis of various organic and organometallic compounds. It can also be utilized in the development of advanced materials and in chemical research. Due to its unique structure and reactivity, (2-(2,6-dimethoxyphenyl)ethynyl)trimethylsilane is of interest to scientists and researchers in the fields of chemistry, materials science, and chemical engineering.

Uses

Used in Chemical Synthesis:
(2-(2,6-dimethoxyphenyl)ethynyl)trimethylsilane is used as a precursor in the synthesis of various organic and organometallic compounds for [application reason].
Used in Advanced Materials Development:
(2-(2,6-dimethoxyphenyl)ethynyl)trimethylsilane is used as a component in the development of advanced materials for [application reason].
Used in Chemical Research:
(2-(2,6-dimethoxyphenyl)ethynyl)trimethylsilane is used as a subject of study in chemical research for [application reason].

Upstream product

• 16932-44-8 2-iodo-1,3-dimethoxybenzene 
• 1066-54-2 trimethylsilylacetylene 

Downstream Products

• 126829-31-0 1-ethynyl-2,6-dimethoxybenzene 
• 2040-04-2 2,6-dimethoxyacetophenone 
• 1321913-81-8 7-benzyl-4-methyl-5-[2-(2,6-dimethoxyphenyl)ethyl]-7H-pyrrolo[2,3-d]pyrimidin-2-amine 
• 1321914-09-3 N-{7-benzyl-4-methyl-5-[(2,6-dimethoxyphenyl)ethyl]-7H-pyrrolo[2,3-d]pyrimidin-2-yl}-N-(2,2-dimethylpropanoyl)-2,2-dimethylpropanamide 
• 1321913-96-5 N-{7-benzyl-4-methyl-5-[(2,6-dimethoxyphenyl)ethynyl]-7H-pyrrolo[2,3-d]pyrimidin-2-yl}-N-(2,2-dimethylpropanoyl)-2,2-dimethylpropanamide 

Relevant articles and documents

Reactivity switch enabled by counterion: Highly chemoselective dimerization and hydration of terminal alkynes

A counterion-controlled reactivity tuning in Pd-catalyzed highly chemoselective and regioselective dimerization and hydration of terminal alkynes is reported. The use of acetate as counterion favors the formation of an alkenyl alkynyl palladium intermediate which forms hitherto less reported 1,3-diaryl-substituted conjugated enynes after reductive elimination. Using chloride, which is a better leaving group, leads to anion exchange on the alkenylpalladium intermediate with hydroxide which after reductive elimination and tautomerization delivered the hydration products.

Ortho, ortho′-Substituted KITPHOS monophosphines: Highly efficient ligands for palladium-catalyzed C-C and C-N bond formation

ortho, ortho′-Substitution of the phosphinoalkyne-derived aryl ring in KITPHOS (11-dicyclohexylphosphino-12-phenyl-9,10-ethenoanthracene) monophosphines enhances the performance of this class of ligand in palladium-catalyzed Suzuki-Miyaura cross-couplings and BuchwaldHartwig aminations, compared with their unsubstituted and mono-substituted counterparts. An alternative complementary synthesis of KITPHOS monophosphines has been developed and two new members of this family, 2,6-Me2-KITPHOS [11-dicyclohexylphosphino-12-(2,6-dimethylphenyl)-9,10-ethenoanthracene] and 2,6-(MeO)2-KITPHOS [11-dicyclohexylphosphino-12-(2,6-dimethoxyphenyl)-9,10-ethenoanthracene], have been prepared; palladium complexes of both are highly efficient catalysts for C - C and C - N bond formation with a range of electron-rich and electron-poor aromatic chlorides as well as heteroaryl chlorides.