1242769-19-2

Basic information

• Product Name: Tsi(p-ClC₆H₄)SiCl₂
• CAS NO: 1242769-19-2
• Molecular Weight: 442.123
• Mol File: 1242769-19-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Tsi(p-ClC₆H₄)SiCl₂(CAS DataBase Reference)
• NIST Chemistry Reference: Tsi(p-ClC₆H₄)SiCl₂(1242769-19-2)
• EPA Substance Registry System: Tsi(p-ClC₆H₄)SiCl₂(1242769-19-2)

Safety Data

• Hazardous Substances Data: 1242769-19-2(Hazardous Substances Data)

Upstream product

• 825-94-5 trichloro(p-chlorophenyl)silane 
• 28830-22-0 tris(trimethylsilyl)methyllithium 

Relevant articles and documents

Synthesis and characterization of new aromatic-group substituted silanes bearing tris (trimethylsilyl)methyl bulky groups

Reaction of the Grignard reagent, p-ClC6H4MgCl, with SiCl4 in toluene gave (p-ClC6H4) 2SiCl2, which was treated with KHF2 to give (p-ClC6H4)2SiF2 (1). Reaction of the latter with [(Me3Si)3C]Li in THF leads to the preparation of [(Me3Si)3C](p-ClC6H4) 2SiF (2). Treatment of (2) with LiAlH4 gave [(Me 3Si)3C](p-ClC6H4)2SiH (3) and [(Me3Si)3C](p-ClC6H4)(C 6H5)SiH (4). [(Me3Si)3C](p-ClC 6H4)SiCl2 (5) was also prepared from the reaction of (p-ClC6H4)SiCl3 with [(Me 3Si)3C]Li in a similar manner. The new highly sterically hindered organosilicon reagents (2) to (5) have been fully characterized by IR, 1H and 13C NMR, and mass spectrometry as well as elemental analysis. Copyright Taylor & Francis Group, LLC.