1242772-59-3

Basic information

• Product Name: 1,3-(Bu₃Sn)2-2,4,5-C₆HF₃
• CAS NO: 1242772-59-3
• Molecular Weight: 710.182
• Mol File: 1242772-59-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-(Bu₃Sn)2-2,4,5-C₆HF₃(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-(Bu₃Sn)2-2,4,5-C₆HF₃(1242772-59-3)
• EPA Substance Registry System: 1,3-(Bu₃Sn)2-2,4,5-C₆HF₃(1242772-59-3)

Safety Data

• Hazardous Substances Data: 1242772-59-3(Hazardous Substances Data)

Upstream product

• 367-23-7 1,2,4-trifluorobenzene 
• 7486-35-3 tri-n-butyl(vinyl)tin 

Relevant articles and documents

Catalytic C-H bond stannylation: A new regioselective pathway to C-Sn bonds via C-H bond functionalization

The ubiquitous Stille coupling reaction utilizes Sn-C bonds and is of great utility to organic chemists. Unlike the B-C bonds used in the Miyaura-Suzuki coupling reaction, which are readily obtained via direct borylation of C-H bonds, routes to organotin compounds via direct C-H bond functionalization are lacking. Here we report that the nickel-catalyzed reaction of fluorinated arenes and pyridines with vinyl stannanes does not provide the expected vinyl compounds via C-F activation but rather provides new Sn-C bonds via C-H functionalization with the loss of ethylene. This mechanism provides a new unanticipated methodology for the direct conversion of C-H bonds to carbon-heteroatom bonds.