1243579-13-6

Basic information

• Product Name: C₁₃H₂₈OS
• Synonyms: C₁₃H₂₈OS
• CAS NO: 1243579-13-6
• Molecular Weight: 232.431
• Mol File: 1243579-13-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₃H₂₈OS(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₂₈OS(1243579-13-6)
• EPA Substance Registry System: C₁₃H₂₈OS(1243579-13-6)

Safety Data

• Hazardous Substances Data: 1243579-13-6(Hazardous Substances Data)

Upstream product

• 7341-17-5 2-ethylhexane-1-thiol 
• 2550-26-7 4-Phenyl-2-butanone 
• 72345-23-4 (2S,4S)-pentane-2,4-diol 

Relevant articles and documents

Asymmetric reduction of aliphatic ketones and acyl silanes using chiral anti-pentane-2,4-diol and a catalytic amount of 2,4-dinitrobenzenesulfonic acid

Aliphatic ketones were reduced to the corresponding secondary alcohols by using anti-1,3-diol and a catalytic amount of 2,4-dinitrobenzenesulfonic acid (DNBSA) in benzene at reflux. Addition of 1-octanethiol in that media improved the efficiency of the reduction. Asymmetric reduction of aliphatic ketones was performed by using chiral anti-pentane-2,4-diol, and highly asymmetric induction (up to >99% ee) was observed in the reduction of tert-alkyl ketones. Asymmetric reduction of acyl silanes using chiral anti-pentane-2,4-diol and DNBSA proceeded efficiently in the absence of octanethiol and the corresponding α-silyl alcohols were obtained in high yields with high ees.