124372-27-6Relevant articles and documents
Matrix Studies of the Photolysis of o-Carbomethoxyphenyldiazomethane. Direct Observation of Carbonyl Ylide and Its Photoinduced Valence Tautomerization
Murata, Shigeru,Ohtawa, Yasuki,Tomioka, Hideo
, p. 853 - 856 (2007/10/02)
Photoreactions of o-carbomethoxyphenyldiazomethane (1), in Ar matrix at 10 K are studied by means of infrared spectroscopy.Irradiation (>350 nm) of 1 generates the carbonyl ylide, which undergoes the reversible photo-isomerization to the corresponding oxi