1244340-81-5

Basic information

• Product Name: (Al₄(CH₃)4(NHC₆H₃(CH(CH₃)2)2)4(((CH₃)2CH)2C₆H₃NC(C₆H₄C(CH₃)3)N)2)
• CAS NO: 1244340-81-5
• Molecular Weight: 1542.2
• Mol File: 1244340-81-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Al₄(CH₃)4(NHC₆H₃(CH(CH₃)2)2)4(((CH₃)2CH)2C₆H₃NC(C₆H₄C(CH₃)3)N)2)(CAS DataBase Reference)
• NIST Chemistry Reference: (Al₄(CH₃)4(NHC₆H₃(CH(CH₃)2)2)4(((CH₃)2CH)2C₆H₃NC(C₆H₄C(CH₃)3)N)2)(1244340-81-5)
• EPA Substance Registry System: (Al₄(CH₃)4(NHC₆H₃(CH(CH₃)2)2)4(((CH₃)2CH)2C₆H₃NC(C₆H₄C(CH₃)3)N)2)(1244340-81-5)

Safety Data

• Hazardous Substances Data: 1244340-81-5(Hazardous Substances Data)

Upstream product

• 4210-32-6 4-tert-butyl benzonitrile 

Relevant articles and documents

Reactions of an aluminum amide with aromatic nitriles: Formation of Al-N-C frameworks

Reactions of a four-membered Al-N ring, [(Dipp)HNAlMe2] 2 (2; Dipp =2,6-diisopropylphenyl), with the aromatic nitriles PhCN, TbpCN (Tbp =4-tert-butylphenyl), DmpCN (Dmp = 2,6-dimethylphenyl), DepCN (DepCN = 2,6-diethylphenyl), and DippCN are reported. 2 reacts with PhCN to give a 1:2 insertion product, the tetrameric aluminum amidinate 3, whereas with TbpCN it gives the 1:1 insertion products 4-6. Under similar conditions, DmpCN, DepCN, and DippCN do not undergo insertion but form simple adducts of alumazene (1), 7a-c and 8a-c (2:1 and 1:1 nitrile/alumazene), in which the nitriles coordinate to Al. Compounds 3-6 and 7a-c have been structurally characterized. 3 is comprised of four four-membered aluminum amidinate rings. 5 features a core made of three Al2N2 and two AlCN2 four-membered rings fused together. The structures of 4 and 6 consist of a dimer of a six-membered Al2CN3 framework. A high-yield synthesis of 3 from N-(Dipp)benzamidine and AlMe3 has also been reported.