124482-22-0

Basic information

• Product Name: {(4S,4aS)-6,7-Dimethoxy-1-[(Z)-phenylimino]-4,4a,9,10-tetrahydro-3H-2-thia-10a-aza-phenanthren-4-yl}-methanol
• Synonyms: {(4S,4aS)-6,7-Dimethoxy-1-[(Z)-phenylimino]-4,4a,9,10-tetrahydro-3H-2-thia-10a-aza-phenanthren-4-yl}-methanol
• CAS NO: 124482-22-0
• Molecular Weight: 384.499
• Mol File: 124482-22-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {(4S,4aS)-6,7-Dimethoxy-1-[(Z)-phenylimino]-4,4a,9,10-tetrahydro-3H-2-thia-10a-aza-phenanthren-4-yl}-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: {(4S,4aS)-6,7-Dimethoxy-1-[(Z)-phenylimino]-4,4a,9,10-tetrahydro-3H-2-thia-10a-aza-phenanthren-4-yl}-methanol(124482-22-0)
• EPA Substance Registry System: {(4S,4aS)-6,7-Dimethoxy-1-[(Z)-phenylimino]-4,4a,9,10-tetrahydro-3H-2-thia-10a-aza-phenanthren-4-yl}-methanol(124482-22-0)

Safety Data

• Hazardous Substances Data: 124482-22-0(Hazardous Substances Data)

Upstream product

• 103-72-0 phenyl isothiocyanate 
• 124482-06-0 Benzoic acid (S)-2-((S)-6,7-dimethoxy-2-phenylthiocarbamoyl-1,2,3,4-tetrahydro-isoquinolin-1-yl)-3-hydroxy-propyl ester 
• 124482-07-1 Benzoic acid (R)-2-((S)-6,7-dimethoxy-2-phenylthiocarbamoyl-1,2,3,4-tetrahydro-isoquinolin-1-yl)-3-hydroxy-propyl ester 
• 113583-46-3 Benzoic acid (S)-2-((R)-6,7-dimethoxy-1,2,3,4-tetrahydro-isoquinolin-1-yl)-3-hydroxy-propyl ester 
• 113583-45-2 Benzoic acid (R)-2-((R)-6,7-dimethoxy-1,2,3,4-tetrahydro-isoquinolin-1-yl)-3-hydroxy-propyl ester 
• 98661-42-8 1--6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline 
• 99082-55-0 3,4-dihydro-1-[2-hydroxy-1-(hydroxymethyl)ethyl]-6,7-dimethoxy-N-phenyl-2(1H)-isoquinolinecarbothioamide 
• 124482-16-2 {(4S,4aS)-6,7-Dimethoxy-1-[(Z)-phenylimino]-4,4a,9,10-tetrahydro-3H-2-oxa-10a-aza-phenanthren-4-yl}-methanol 

Downstream Products

• 124482-09-3 Benzoic acid (4S,4aS)-6,7-dimethoxy-1-[(Z)-phenylimino]-4,4a,9,10-tetrahydro-3H-2-thia-10a-aza-phenanthren-4-ylmethyl ester 

Relevant articles and documents

Synthesis and Stereochemistry of Stereoisomeric 1,3-Oxazino- and 1,3-Thiazinoisoquinolines

Starting from the 6,7-dialkoxy-1--1,2,3,4-tetrahydroisoquinolines 2 and 3, the 4-imino-substituted 1-(hydroxymethyl)-9,10-dialkoxy-2H,4H-1,6,7,11b-tetrahydro-1,3-oxazino- and -thiazinoisoquinoline diastereomers 6a-c, 7a-c, 8a-c, 9a-c, 14, and 15 and the 4-substituted 1,6,7,11b-tetrahydro-1,3-oxazinoisoquinoline diastereomers 16-24 were prepared.The relative configurations and the predominant conformation of these products were determined by NMR spectroscopy and for 18 by X-ray diffraction methods.The prepared 1,3-oxazinoisoquinoline diastereomers have predominantly trans conformations (16, 18, 22, 23), whereas cis conformations (cis-A) prevail for 20, 21 and 24.Thus, the first evidence for either trans- or cis-A conformations in 1,3-oxazinoisoquinolines is presented.