124535-65-5

Basic information

• Product Name: (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride
• Synonyms: (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride
• CAS NO: 124535-65-5
• Molecular Weight: 884.969
• Mol File: 124535-65-5.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride(CAS DataBase Reference)
• NIST Chemistry Reference: (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride(124535-65-5)
• EPA Substance Registry System: (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride(124535-65-5)

Safety Data

• Hazardous Substances Data: 124535-65-5(Hazardous Substances Data)

Upstream product

• 16940-66-2 sodium tetrahydroborate 
• 85990-32-5 (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide 
• 67-56-1 methanol 
• 121393-39-3 5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) 
• 1556-09-8 cyclooctyl bromide 
• 292-64-8 Cyclooctan 
• 161407-97-2 (5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride 
• 7732-18-5 water 
• 108-88-3 toluene 
• 124535-66-6 (tetramesitylporphyrinato)rhodium(I) 
• 121393-39-3 (tetramesitylporphyrinato)rhodium(II) 
• 34557-54-5 methane 

Downstream Products

• 121393-39-3 5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) 
• 927403-44-9 ethyl (5,10,15,20-tetramesitylporphyrinato)rhodium(III) acetate 
• 927403-46-1 Rh(tetramesitylporphyrin)CHDCO₂Et 
• 940002-35-7 (5,10,15,20-tetramesitylporphyrinato)-1-imino-2-methyl-2-phenylpropylrhodium(III) 
• 1234321-55-1 (5,10,15,20-tetramesitylporphyrinato)(3-phenylpropyl)rhodium(III) 
• 940002-36-8 propyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III) 
• 85990-32-5 (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide 

Relevant articles and documents

Ligand effect on the rhodium porphyrin catalyzed hydrogenation of [2.2]paracyclophane with water: Key bimetallic hydrogenation

Rhodium porphyrin catalyzed hydrogenation of the aliphatic carbon-carbon σ-bond of [2.2]paracyclophane with water has been examined with a variety of tetraarylporphyrins and axial ligands. Mechanistic investigations show that RhIII(ttp)H, which can be derived from the reaction of [RhII(ttp)]2 with water without a sacrificial reductant, plays an important role in promoting bimetallic reductive elimination to give the hydrogenation product.

Room-temperature selective aliphatic carbon-carbon bond activation and functionalization of ethers by rhodium(II) porphyrin

Selective aliphatic carbon(α)-carbon(β) bond activation of ethers by (5,10,15,20-tetramesitylporphyrinato)rhodium(II) (Rh(tmp) (1)) was achieved at room temperature to yield corresponding rhodium porphyrin alkyls and the functionalized esters. Rh(tmp)OH was the proposed intermediate responsible for cleaving the C(α)-C(β) bond. The reaction is general for both straight- and branch-chain ethers.

Metalloradical-catalyzed aliphatic carbon-carbon activation of cyclooctane

The aliphatic carbon-carbon activation of c-octane was achieved via the addition of Rh(ttp)H to give Rh(ttp)( n-octyl) in good yield under mild reaction conditions. The aliphatic carbon-carbon activation was RhII(ttp)- catalyzed and was very se