124887-91-8

Basic information

• Product Name: 2,2-dimethoxyethyl cinnamate
• Synonyms: 2,2-dimethoxyethyl cinnamate
• CAS NO: 124887-91-8
• Molecular Weight: 236.268
• Mol File: 124887-91-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2-dimethoxyethyl cinnamate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-dimethoxyethyl cinnamate(124887-91-8)
• EPA Substance Registry System: 2,2-dimethoxyethyl cinnamate(124887-91-8)

Safety Data

• Hazardous Substances Data: 124887-91-8(Hazardous Substances Data)

Upstream product

• 30934-97-5 2,2-dimethoxyethanol 
• 102-92-1 Cinnamoyl chloride 

Downstream Products

• 134856-19-2 syn-2,2-dimethoxyethyl 4-methyl-5-oxo-3,5-diphenylpentanoate 
• 134856-19-2 anti-2,2-dimethoxyethyl 4-methyl-5-oxo-3,5-diphenylpentanoate 
• 124888-00-2 syn-2,2-dimethoxyethyl 4-methyl-5-oxo-3-phenylheptanoate 
• 124888-00-2 anti-2,2-dimethoxyethyl 4-methyl-5-oxo-3-phenylheptanoate 
• 134856-20-5 anti-2,2-dimethoxyethyl 3-(2-oxocyclohexyl)-3-phenylpropanoate 

Relevant articles and documents

The highly syn-selective Michael reaction of enamines with 2-(1-alkenyl)-1,3-dioxolan-2-ylium cations generated from 2,2-dimethoxyethyl 2-alkenoates in situ

2,2-Dimethoxyethyl 2-alkenoates are easily transformed into 2-(1-alkenyl)-1,3-dioxolan-2-ylium cations in situ on the action of titanium tetrachloride, which react with enamines to predominantly give syn Michael adducts in good yields. This is the first example of such a high syn-selectivity for the Michael reaction of α,β-unsaturated ester derivatives with ketone enolate equivalents.