1251579-64-2Relevant articles and documents
Chain-extension reactions via insitu capture of the dibromofluoromethide ion with difluoromethylene fluoro-olefins
Burton, Donald J.,Hansen, Steven W.
experimental part, p. 41 - 54 (2010/09/04)
The insitu reaction of triphenylphosphine, tribromofluoromethane, and a difluoromethylene olefin successfully allows the capture of the intermediate dibromofluoromethide ion. With fluorinated propenes, the product is an allylic dibromofluoromethyl alkene; with longer chain fluoro-olefins the major product is a 1-bromo-1,3-fluorinated diene derivative. Pentafluoropyridine yields 4-dibromofluoromethyltetrafluoropyridine.