125258-42-6Relevant articles and documents
Addition of trifluoromethanethio- and trifluoromethaneseleno-sulfonates to olefins. Synthesis of vinyl triflones
Billard, Thierry,Langlois, Bernard R.
, p. 8065 - 8074 (2007/10/03)
Trifluoromethanethio- and trifluoromethaneselenosulfonates are strong electrophilic reagents which add rapidly to olefins to deliver β-sulfenyl and β-selenyl triflones. These products are converted in high yields to vinyl triflones by different techniques
A new route to thio- and selenosulfonates from disulfides and diselenides. Application to the synthesis of new thio- and selenoesters of triflic acid
Billard, Thierry,Langlois, Bernard R.,Large, Sylvie,Anker, Daniel,Roidot, Nathalie,Roure, Philippe
, p. 7545 - 7550 (2007/10/03)
Alkyl and aryl trifluoromethanethiosulfonates1 (or selenosulfonates) were prepared in one step either from alkyl and aryl sulfenyl (or selenenyl) chlorides and sodium trifluoromethanesulfinate (3) or, more generally, from disulfides (or diselenides), 3, and bromine. The second method involved trifluoromethanesulfonyl bromide as key intermediate. Benzenethiosulfonates were obtained in a similar way from disulfides, benzenesulfinate, and bromine but benzeneselenosulfonates could not be obtained by the same method from diselenides.
