125288-33-7

Basic information

• Product Name: 2-chloroethyl 4-methyl benzoate
• Synonyms: 2-chloroethyl 4-methyl benzoate
• CAS NO: 125288-33-7
• Molecular Weight: 198.649
• Mol File: 125288-33-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-chloroethyl 4-methyl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chloroethyl 4-methyl benzoate(125288-33-7)
• EPA Substance Registry System: 2-chloroethyl 4-methyl benzoate(125288-33-7)

Safety Data

• Hazardous Substances Data: 125288-33-7(Hazardous Substances Data)

Upstream product

• 874-60-2 4-methyl-benzoyl chloride 
• 107-06-2 1,2-dichloro-ethane 
• 895-85-2 di-(4-methylbenzoyl)peroxide 
• 2403-51-2 2-(4-methylphenyl)-1,3-dioxolane 
• 4079-54-3 2-hydroxy-1-p-tolyl-ethanone 

Downstream Products

• 1093252-48-2 (+/-)-3'-O-(p-toluoyl)dyphylline 
• 99-94-5 p-Toluic acid 

Relevant articles and documents

An Effective Method for the Construction of Esters Using Cs2CO3 as Oxygen Source

An effective method for the construction of esters from acyl chloride and halohydrocarbon using Cs2CO3 as an oxygen source was achieved for the first time. The methodology has a wide scope of substrates and can be scaled up. The study of a preliminary reaction mechanism demonstrated that the O in the products comes from Cs2CO3 and this esterification proceeds through a free radical reaction. It was also found that CO2 can also be used in this esterification reaction as an oxygen source.

Copper-catalyzed Csp3-O cross-coupling of unactivated alkyl halides with organic peroxides

An efficient Cu-catalyzed Csp3-O coupling of peroxides with haloalkanes is described. High yields of products were achieved under mild conditions. Significantly, in addition to primary alkyl halides, secondary alkyl halogenated hydrocarbons could also be applied to this system. The new reaction system could tolerate a wide range of organic peroxides.

A new synthetic method for haloalkyl carboxylic esters from the radical ring cleavage of cyclic acetals with haloform

A one-pot reaction of cyclic acetals with haloform catalyzed by AIBN(2,2'-azobisisobutyronitrile) provides a novel convenient way to prepare directly haloalkyl carboxylic esters in good yields.