1253101-17-5Relevant articles and documents
Cu(I)-catalyzed carboxylative coupling of terminal alkynes, allylic chlorides, and CO2
Zhang, Wen-Zhen,Li, Wen-Jie,Zhang, Xiao,Zhou, Hui,Lu, Xiao-Bing
supporting information; experimental part, p. 4748 - 4751 (2010/12/25)
A highly selective synthesis of a variety of functionalized allylic 2-alkynoates was realized via the carboxylative coupling of terminal alkynes, allylic chlorides, and CO2 catalyzed by the N-heterocyclic carbene copper(I) complex (IPr)CuCl. The catalyst can be easily recovered without any loss in activity and product selectivity.