125405-88-1

Basic information

• Product Name: tributyl(1-phenylprop-1-en-1-yl)stannane
• CAS NO: 125405-88-1
• Molecular Weight: 407.227
• Mol File: 125405-88-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: tributyl(1-phenylprop-1-en-1-yl)stannane(CAS DataBase Reference)
• NIST Chemistry Reference: tributyl(1-phenylprop-1-en-1-yl)stannane(125405-88-1)
• EPA Substance Registry System: tributyl(1-phenylprop-1-en-1-yl)stannane(125405-88-1)

Safety Data

• Hazardous Substances Data: 125405-88-1(Hazardous Substances Data)

Upstream product

• 673-32-5 1-Phenylprop-1-yne 
• 688-73-3 tri-n-butyl-tin hydride 

Downstream Products

• 301-04-2 lead acetate 
• 611-31-4 1H-2,3-benzoxazin-1-one 
• 1310481-67-4 1-nitro-2-(1-phenyl-1-propen-1-yl)benzene 
• 4757-69-1 2-methyl-3-phenyl-1H-indole 
• 605-03-8 4-phenylquinoline 

Relevant articles and documents

Catalytic Dehydrogenative Stannylation of C(sp)-H Bonds Involving Cooperative Sn-H Bond Activation of Hydrostannanes

The catalytic generation of a stannylium-ion-like tin electrophile by heterolytic cleavage of the Sn-H bond in hydrostannanes at the Ru-S bond of Ohki-Tatsumi complexes is reported. Reacting these activated hydrostannanes with terminal acetylenes does not lead to hydrostannylation of the C-C triple bond but to dehydrogenative stannylation of the alkyne terminus. The scope of this rare direct C(sp)-H bond stannylation with hydrostannanes is broad, and a mechanism involving a β-tin-stabilized vinyl cation likely having a bridged structure is presented.

Palladium(0) Catalyzed Hydrostannylation of Alkynes. Stereospecific Syn Addition of Tributyltin Hydride

Tetrakis(triphenylphosphine)palladium(0) catalyzes the hydrostannylation of alkynes to give vinylstannanes in excellent yields.This reaction proceeds in syn manner.