125414-52-0

Basic information

• Product Name: Carbamic acid, (1-formyl-1-methyl-2-propynyl)-, 1,1-dimethylethyl ester, (R)-
• Synonyms: Carbamic acid, (1-formyl-1-methyl-2-propynyl)-, 1,1-dimethylethyl ester, (R)-
• CAS NO: 125414-52-0
• Molecular Formula: C10H15NO3
• Molecular Weight: 197.231
• Product Categories: N-BOC
• Mol File: 125414-52-0.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Carbamic acid, (1-formyl-1-methyl-2-propynyl)-, 1,1-dimethylethyl ester, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (1-formyl-1-methyl-2-propynyl)-, 1,1-dimethylethyl ester, (R)-(125414-52-0)
• EPA Substance Registry System: Carbamic acid, (1-formyl-1-methyl-2-propynyl)-, 1,1-dimethylethyl ester, (R)-(125414-52-0)

Safety Data

• Hazardous Substances Data: 125414-52-0(Hazardous Substances Data)

Upstream product

• 125414-48-4 [(R)-1-((R)-1,2-Dihydroxy-ethyl)-1-methyl-prop-2-ynyl]-carbamic acid tert-butyl ester 
• 125414-26-8 2,2,2-Trichloro-acetimidic acid (2R,3S)-3-ethynyl-3-methyl-oxiranylmethyl ester 
• 125414-39-3 (4R,5R)-4-Ethynyl-4-methyl-2-trichloromethyl-5,6-dihydro-4H-[1,3]oxazin-5-ol 
• 118759-65-2 (2S,3S)-3-Ethynyl-2-hydroxymethyl-3-methyloxirane 
• 6153-06-6 (E)-3-methylpent-2-en-4-yn-1-ol 

Relevant articles and documents

Amino Acids and Peptides; 70. Optically Active α-Amino Acids, N-Boc-Aminoaldehydes and α-Amino-β-hydroxy Acids from 2,3-Epoxy Alcohols

Trichloroacetimidic esters of 2,3-epoxy alcohols are transformed into oxazolines 5 and dihydrooxazines 6, respectively, depending on the structure of the educts and the catalyst.The five-membered ring compounds 5 are transformed into erythro-α-amino-β-hydroxy acids (60-70percent from epoxy alcohols) via axazolidinones 11, 12, and 13. α-Amino acids and α-substituted α-amino acids 10 as well as the corresponding aldehydes 9 are obtained from the dihydrooxazines 6 (50-60percent from epoxy alcohols).